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Detailed study about oxidizing alcohols to aldehydes by TEMPO free radical
This article is mainly about the principle of TEMPO free radical(2,2,6,6-tetramethylpiperidine-1-oxyl, 2564-83-2) oxidation, why the reaction can be selective and how to reduce the consumption of TEMPO. Presented by NanJing Liskon Biological Technology Co.,ltd.
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TEMPO oxidizes alcohols to aldehydes and ketones
TEMPO oxidizes alcohols to aldehydes and ketonesIn 1987, Anelli reported the oxidation of alcohols to aldehydes and ketones using TEMPO (CA.1% mol), NaOCl, KBr and NaHCO3 in dichloromethane - water two-phase solvent.TEMPO also called 2,2,6,6-tetramethylpiperidine-1-oxide, or 2,2,6,6-tetramethylpiper
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Discussion about TEMPO
QUESTION:TEMPO ((2,2,6,6-tetramethylpiperidin-1-yl)oxyl, or (2,2,6,6-tetramethylpiperidin-1-yl)oxidanyl),Given that it's a free radical, why doesn't it react with itself, despite being capable of reacting with other radicals in the system itself)?In addition, according to Wikipedia, it's a red-orang
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TEMPO-Oxidizer&catalyst with excellent stability
Oxidizers and catalysts are widely used in medicines and pesticides production. 2,2,6,6-tetramethylpiperidinyloxy(CAS:2564-83-2), commonly known as TEMPO, can be used both ways, and it has excellent stability in storage condition.Following is chemical properties of TEMPO:Appearance: red crystalMolec
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